That's a flawed metric, because even though we have 320 million people in this country, police certainly do not come in contact with 320 million people. It would be better to compare both numbers to the number of contacts between civilians and police (whatever that number is). As those are the opportunities where either:
a.) a police officer can be killed by a civilian
b.) a civilian can be killed by a police officer.
c.) neither is killed by the other.